The phosphorylation of glucose is represented by the unfavorable reaction

CHEMISTRY · Single correct · AP · Chemistry · Thermodynamics and Electrochemistry · Thermodynamics and Electrochemistry

Problem

The phosphorylation of glucose is represented by the unfavorable reaction Glucose+Pi→Glucose-6-P+H2O(ΔG∘>0)\text{Glucose}+\text{P}_\text{i} \rightarrow \text{Glucose-6-P}+\text{H}_2\text{O} \quad (\Delta G^{\circ}>0). Which of the following favorable reactions, when combined with the one above, is most likely to yield an overall negative ΔG∘\Delta G^{\circ}? (a) ADP+Pi  →  ATP+H2O\text{ADP}+\text{P}_\text{i}\;\rightarrow\;\text{ATP}+\text{H}_2\text{O} (b) ATP+H2O  →  AMP+2 Pi\text{ATP}+\text{H}_2\text{O}\;\rightarrow\;\text{AMP}+2\,\text{P}_\text{i} (c) ATP+H2O  →  ADP+Pi\text{ATP}+\text{H}_2\text{O}\;\rightarrow\;\text{ADP}+\text{P}_\text{i} (d) 2 Pi  →  P2O74−+H2O2\,\text{P}_\text{i}\;\rightarrow\;\text{P}_2\text{O}_7^{4-}+\text{H}_2\text{O}

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