Consider the gaseous equilibrium established in a sealed vessel at with a total…

CHEMISTRY · Single correct · A Level · Chemistry · Chemical equilibria (Le Chatelier’s principle and Kc) · Chemical equilibria (Le Chatelier’s principle and Kc)

Problem

Consider the gaseous equilibrium 2A(g)⇌B(g)2\text{A}(g)\rightleftharpoons \text{B}(g) established in a sealed 10.0 L10.0\,\text{L} vessel at 500 K500\,\text{K} with a total pressure of 2.00 atm2.00\,\text{atm}. The volume of the vessel is suddenly decreased to 5.00 L5.00\,\text{L} at constant temperature. Which statement best describes the system immediately after the compression? (a) Q ⁣p>K ⁣pQ_{\!p}>K_{\!p} and the reaction will shift toward reactants. (b) Q ⁣p=K ⁣pQ_{\!p}=K_{\!p} so no shift will occur. (c) Q ⁣p<K ⁣pQ_{\!p}<K_{\!p} and the reaction will shift toward products. (d) Q ⁣p<K ⁣pQ_{\!p}<K_{\!p} and the reaction will shift toward reactants.

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