An acid solution of sample containing 26.83 mg of combined rhenium was reduced by…

CHEMISTRY · Subjective · CBSE · Chemistry · Redox Reactions · Redox Reactions

Problem

An acid solution of KReO4\text{KReO}_4 sample containing 26.83 mg of combined rhenium was reduced by passage through a column of granulated zinc. The effluent solution including the washings from the column, was then titrated with 0.05 N KMnO4\text{KMnO}_4. 11.45 mL of the standard KMnO4\text{KMnO}_4 was required for the reoxidation of all the rhenium to the perrhenate ion ReO4−\text{ReO}_4^-. Assuming that rhenium was the only element reduced, what is the oxidation state to which rhenium was reduced by the zinc column?

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