Equal volumes (50 mL each) of 0.10 M and 0.10 M are mixed

CHEMISTRY · Single correct · AP · Chemistry · Chemical Reactions · Chemical Reactions

Problem

Equal volumes (50 mL each) of 0.10 M Na2CO3(aq)\text{Na}_2\text{CO}_3(aq) and 0.10 M BaCl2(aq)\text{BaCl}_2(aq) are mixed. Solid BaCO3\text{BaCO}_3 precipitates and settles out. Which particulate-level description best represents the species that should appear in a diagram of the remaining solution above the solid? (a) Only Na+\text{Na}^{+} ions solvated by water remain; the Cl−\text{Cl}^{-} ions have precipitated with Ba2+\text{Ba}^{2+} as solid BaCl2\text{BaCl}_{2}. (b) Solvated Na+,  Cl−,  CO32−\text{Na}^{+},\;\text{Cl}^{-},\;\text{CO}_{3}^{2-} ions are present; no Ba2+\text{Ba}^{2+} ions remain in the solution. (c) Only Na+\text{Na}^{+} and Cl−\text{Cl}^{-} ions in roughly equal numbers, each solvated by water molecules; no Ba2+\text{Ba}^{2+} or CO32−\text{CO}_{3}^{2-} ions remain in solution. (d) Solvated Na+,  Cl−,  Ba2+\text{Na}^{+},\;\text{Cl}^{-},\;\text{Ba}^{2+} ions are present in equal numbers; CO32−\text{CO}_{3}^{2-} ions are absent because all carbonate precipitated.

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