A sample of 2.00 mol of an ideal diatomic gas at and 1.20 L undergoes a reversible…

CHEMISTRY · Multi-part · A Level · Chemistry · Thermodynamics · Thermodynamics

Problem

A sample of 2.00 mol of an ideal diatomic gas at 400 K400\,\text{K} and 1.20 L undergoes a reversible isothermal expansion against a piston until its volume reaches 3.00 L. The gas behaves ideally throughout, and R=8.314 J mol−1 K−1R=8.314\,\text{J mol}^{-1}\,\text{K}^{-1}. (a) Calculate the entropy change for the gas during the expansion. (b) If the same final state were reached instead by first expanding the gas adiabatically to 2.40 L and then heating it isochorically to 400 K400\,\text{K}, would the total entropy change for the gas differ from that in part (a)? Explain your answer without performing additional calculations.

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