A laboratory route for preparing aqueous calcium chloride involves reacting solid…

CHEMISTRY · Multi-part · A Level · Chemistry · Energetics · Energetics

Problem

A laboratory route for preparing aqueous calcium chloride involves reacting solid calcium carbonate with hydrochloric acid, followed by dissolving the gaseous carbon dioxide produced. The simplified sequence at 298 K is described below.
StepChemical transformationΔH (kJ mol⁻¹)
1CaCO₃(s) + 2 HCl(aq) → CaCl₂(aq) + H₂O(l) + CO₂(g)–171.5
2CO₂(g) → CO₂(aq)–19.4
Assume that the aqueous solutions are sufficiently dilute to treat them as ideal. (a) Write the overall balanced chemical equation for producing CaCl₂(aq) with dissolved CO₂ starting from CaCO₃(s) and HCl(aq). (b) Calculate the overall enthalpy change (in kJ mol⁻¹ of CaCl₂ produced) for the two-step sequence. (c) Explain qualitatively how the dissolution of CO₂ affects the net enthalpy change compared with releasing CO₂ as a gas.

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