The compressibility factor for definite mass of a van der Waals' gas at 0∘C and 100 atmosphere is found to be 0.5. Assuming the volume of gas molecules negligible, the van der Waals' constant ' a ' for a gas is :
(1) 1.256 litre2 mol−2 atm
(2) 0.256 litre2 mol−2 atm
(3) 2.256 litre2 mol−2 atm
(4) 0.0256 litre2 mol−2 atm