The formation of the iron(III) thiocyanate complex is represented by Fe ^ 3+ (aq)+…

CHEMISTRY · Single correct · A Level · Chemistry · Chemical equilibria (Le Chatelier’s principle and Kc) · Chemical equilibria (Le Chatelier’s principle and Kc)

Problem

The formation of the iron(III) thiocyanate complex is represented by Fe3+(aq)+SCN−(aq)⇌FeSCN2+(aq)ΔH∘=−8 kJ\text{Fe}^{3+}(aq)+\text{SCN}^-(aq)\rightleftharpoons\text{FeSCN}^{2+}(aq)\qquad\Delta H^{\circ}=-8\text{ kJ} Three separate stresses are applied to identical equilibrium mixtures. I. Add Fe3+(aq)\text{Fe}^{3+}(aq) ions. II. Decrease the temperature by 20 K.20\,\text{K}. III. Dilute the solution by adding an equal volume of water. Which of the following correctly ranks the stresses from greatest to least increase in the equilibrium concentration of FeSCN2+\text{FeSCN}^{2+}? (a) II > I > III (b) I > II > III (c) III > I > II (d) I > III > II

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