Two proposed mechanisms convert A → B

CHEMISTRY · Subjective · AP · Chemistry · Kinetics · Kinetics

Problem

Two proposed mechanisms convert A → B. Mechanism A: highest transition state is 80 kJ·mol⁻¹ above the reactants, and the products are −30 kJ·mol⁻¹ relative to the reactants. Mechanism B: highest transition state is 60 kJ·mol⁻¹ above the reactants, and the products are −10 kJ·mol⁻¹ relative to the reactants. At the same temperature, which mechanism is expected to give the faster overall rate, and which mechanism is more exothermic? State both answers.

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