A sealed vessel at constant temperature contains the reaction

CHEMISTRY · Single correct · A Level · Chemistry · Chemical equilibria (Le Chatelier’s principle and Kc) · Chemical equilibria (Le Chatelier’s principle and Kc)

Problem

A sealed vessel at constant temperature contains the reaction N2(g)+3H2(g)  ⇌  2NH3(g)\text{N}_2(g)+3\text{H}_2(g)\;\rightleftharpoons\;2\text{NH}_3(g). At a particular instant the reaction quotient QQ is found to be greater than the equilibrium constant KK. Which of the following best describes how the partial pressures of the species will change as the system approaches equilibrium? (a) pNH3p_{\text{NH}_3} will decrease, while pN2p_{\text{N}_2} and pH2p_{\text{H}_2} will increase. (b) pNH3p_{\text{NH}_3} will increase, while pN2p_{\text{N}_2} and pH2p_{\text{H}_2} will decrease. (c) All partial pressures will remain unchanged because the system is already at equilibrium. (d) pNH3p_{\text{NH}_3} will decrease, pN2p_{\text{N}_2} will decrease, and pH2p_{\text{H}_2} will increase.

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