Potassium iodide, KI(s)

CHEMISTRY · Multi-part · A Level · Chemistry · Bonding · Bonding

Problem

Potassium iodide, KI(s), is dissolved in liquid acetone at room temperature. Acetone molecules possess a dipole moment that points from the carbonyl carbon (δ⁺) toward the carbonyl oxygen (δ⁻). A particulate diagram will be constructed to represent a fixed microscopic region that contains 4 K⁺ ions, 4 I⁻ ions, and 20 acetone molecules. (a) Describe the correct orientation of a single acetone molecule with respect to a nearby K⁺ ion. Specify which end of the acetone dipole should face the ion and explain why. (b) Describe the correct orientation of a single acetone molecule with respect to a nearby I⁻ ion. Again, specify which end of the acetone dipole should face the ion and explain why. (c) Without drawing, provide a detailed verbal sketch that a textbook artist could follow to place the 4 K⁺ ions, 4 I⁻ ions, and 20 acetone molecules in the fixed-volume box so that all ion–dipole orientations are depicted correctly. Include approximate relative distances and any symmetry or clustering you expect.

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