A coloured solution known to contain two metal ions

CHEMISTRY · Single correct · ICSE · Chemistry · Analytical Chemistry · Analytical Chemistry

Problem

A coloured solution known to contain two metal ions, was treated with excess cold sodium hydroxide solution. When filtered a whitish solid, slowly changing to brown, was retained on the filter paper and a colourless solution collected as the filtrate. Dropwise addition of hydrochloric acid to the filtrate produced a white ppt. which dissolved in excess acid. Treatment of the residue on filter paper with a solution of strong oxidiser produced a reddish-violet solution. Indicate any pairs of ions: (1) Zn2+\text{Zn}^{2+} and Mn2+\text{Mn}^{2+} ions (2) Mg2+\text{Mg}^{2+} and Zn2+\text{Zn}^{2+} ions (3) Mn2+\text{Mn}^{2+} and Mg2+\text{Mg}^{2+} ions (4) Fe2+\text{Fe}^{2+} and Zn2+\text{Zn}^{2+} ions

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