An unknown element X has the following successive ionization energies (kJ·mol⁻¹): IE₁…

CHEMISTRY · Multi-part · A Level · Chemistry · Periodicity and periodic trends · Periodicity and periodic trends

Problem

An unknown element X has the following successive ionization energies (kJ·mol⁻¹): IE₁ = 737  IE₂ = 1450  IE₃ = 7730  IE₄ = 10500 A second element Y lies immediately to the right of X in the same period of the periodic table. (a) Deduce the most probable group number and ground-state electron configuration of element X. Explain your reasoning based on the ionization-energy data. (b) Provide a qualitative explanation for the very large jump between IE₂ and IE₃ for element X. (c) Compare the effective nuclear attraction experienced by a valence electron in element X with that in element Y, and justify any difference you predict. (d) Predict which of the two elements, X or Y, will have the larger atomic radius. Support your answer with a coherent argument tied to the conclusions from parts (a) through (c).

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