Sulfur tetrafluoride, SF₄

CHEMISTRY · Single correct · AP · Chemistry · Compound Structure and Properties · Compound Structure and Properties

Problem

Sulfur tetrafluoride, SF₄, has an expanded octet around sulfur. In a structure where sulfur is bonded to four fluorine atoms (two axial, two equatorial) with single bonds and possesses one lone pair, which set of formal charges is correct for the molecule? (a) S:+1  ; each F:−12S: +1 \;\text{; each }F: -\dfrac{1}{2} (b) S:0  ; each F:0S: 0 \;\text{; each }F: 0 (c) S:+2  ; each F:−1S: +2 \;\text{; each }F: -1 (d) S:+1  ; one axial F:−1  ; other atoms 0S: +1 \;\text{; one axial }F: -1 \;\text{; other atoms }0

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