When of ethanol,

CHEMISTRY · Subjective · A Level · Chemistry · Energetics · Energetics

Problem

When 5.00 g5.00\,\text{g} of ethanol, C2H5OH(l)\mathrm{C_2H_5OH(l)}, burns completely in O2(g)\mathrm{O_2(g)} at 298 K298\,\text{K} and 1 bar1\,\text{bar}, 148 kJ148\,\text{kJ} of heat is released. All products are formed under standard conditions as CO2(g)\mathrm{CO_2(g)} and H2O(l)\mathrm{H_2O(l)}. Given ΔHf∘(CO2(g))=−393.5 kJ mol−1\Delta H_f^\circ(\mathrm{CO_2(g)}) = -393.5\,\text{kJ mol}^{-1}, ΔHf∘(H2O(l))=−285.8 kJ mol−1\Delta H_f^\circ(\mathrm{H_2O(l)}) = -285.8\,\text{kJ mol}^{-1}, and the molar mass of ethanol is 46.07 g mol−146.07\,\text{g mol}^{-1}, calculate the standard enthalpy of formation, ΔHf∘\Delta H_f^\circ, of C2H5OH(l)\mathrm{C_2H_5OH(l)} in kJ mol−1\text{kJ mol}^{-1}.

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