The equilibrium ( at 350 ,K) is established in a rigid 2.0-L container at 350 ,K

CHEMISTRY · Single correct · A Level · Chemistry · Chemical equilibria (Le Chatelier’s principle and Kc) · Chemical equilibria (Le Chatelier’s principle and Kc)

Problem

The equilibrium 2 NO2(g)⇌N2O4(g)2\,\mathrm{NO_2(g)} \rightleftharpoons \mathrm{N_2O_4(g)} (Kp=0.16K_p=0.16 at 350\,K) is established in a rigid 2.0-L container at 350\,K. Which of the following single changes will cause the greatest shift toward formation of N2_2O4_4? (a) Doubling the temperature at constant volume (b) Compressing the system to 1.0 L1.0\,\text{L} at constant temperature (c) Injecting Ne gas until the total pressure doubles (volume constant) (d) Removing one-half of the NO2_2 while keeping volume and temperature constant

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