In a 1.50 L vessel at 450 °C

CHEMISTRY · Single correct · A Level · Chemistry · Chemical equilibria (Le Chatelier’s principle and Kc) · Chemical equilibria (Le Chatelier’s principle and Kc)

Problem

In a 1.50 L vessel at 450 °C, the initial concentrations of H2(g)\mathrm{H_2(g)} and I2(g)\mathrm{I_2(g)} are each 0.400 M0.400\,\text{M}, and no HI(g)\mathrm{HI(g)} is present. When equilibrium is re-established, the measured concentration of HI\mathrm{HI} is 0.560 M0.560\,\text{M} with an experimental uncertainty of ±0.020 M\pm 0.020\,\text{M}. Which of the following is the best reported value of KcK_{c} for the reaction H2(g)+I2(g)⇌2HI(g)\mathrm{H_2(g)+I_2(g)\rightleftharpoons 2HI(g)} at this temperature? (a) 39 (b) 11 (c) 22 (d) 2.0

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