Two gaseous fuels are considered for a spacecraft thruster

CHEMISTRY · Subjective · A Level · Chemistry · Energetics · Energetics

Problem

Two gaseous fuels are considered for a spacecraft thruster. Fuel 1: CH4\mathrm{CH_4} Fuel 2: C2H4\mathrm{C_2H_4} Combustion reactions (gases throughout): 1. CH4+2 O2→CO2+2 H2O\mathrm{CH_4 + 2\,O_2 \rightarrow CO_2 + 2\,H_2O} 2. C2H4+3 O2→2 CO2+2 H2O\mathrm{C_2H_4 + 3\,O_2 \rightarrow 2\,CO_2 + 2\,H_2O} Average bond energies (kJ mol−1\text{kJ mol}^{-1}): C–H 413, C=C 614, C–C 348, O=O 498, C=O (in CO2_2) 799, O–H 463. Which fuel releases more energy per gram upon complete combustion, and what is that approximate energy release (nearest 1 kJ g−11\,\text{kJ g}^{-1})?

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