A laboratory stock bottle contains

CHEMISTRY · Multi-part · A Level · Chemistry · Acids and bases · Acids and bases

Problem

A laboratory stock bottle contains 0.500 M0.500\,\text{M} HNO3\mathrm{HNO}_{3}. A technician needs 2.00 L2.00\,\text{L} of an acidic rinse solution having pH = 2.60. Assume 25 ∘C25\,^{\circ}\text{C} throughout and that HNO3\mathrm{HNO}_{3} dissociates completely in water. (a) Show, with calculations, whether the stock solution must be diluted or concentrated to reach the target pH. (b) Determine the exact volume of the 0.500 M0.500\,\text{M} stock solution the technician should deliver into a 2.00 L2.00\,\text{L} volumetric flask before diluting to the mark with distilled water. (c) After preparing the solution, the technician measures its temperature and discovers it has warmed to 28 ∘C28\,^{\circ}\text{C}. Discuss qualitatively how (or if) this small temperature increase would alter the pH, citing relevant chemical principles.

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