For the oxidation of nitric oxide

CHEMISTRY · Subjective · AP · Chemistry · Kinetics · Kinetics

Problem

For the oxidation of nitric oxide, a plausible gas-phase mechanism is proposed: Step 1 2NO(g) ⇌ N₂O₂(g) (fast) Step 2 N₂O₂(g) + O₂(g) → 2NO₂(g) (slow) Derive the rate law for the overall formation of NO₂, expressing the rate solely in terms of the concentrations of NO and O₂ and an observed rate constant kobsk_{\text{obs}}.

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