For the catalyzed reaction products

CHEMISTRY · Single correct · A Level · Chemistry · Rate equations · Rate equations

Problem

For the catalyzed reaction 2 A→2\,\mathrm{A}\rightarrow products, the rate law is rate=k′[A][Z]\text{rate}=k'[\mathrm{A}][\mathrm{Z}], where Z\mathrm{Z} is a catalyst that remains at constant concentration during the reaction. With [A]=0.060 M[\mathrm{A}]=0.060\,\text{M} and [Z]=0.0050 M[\mathrm{Z}]=0.0050\,\text{M}, the initial rate is 3.6×10−4 M s−13.6\times10^{-4}\,\text{M\,s}^{-1}. What is the rate when [A][\mathrm{A}] has fallen to 0.020\,M while [Z][\mathrm{Z}] is still 0.0050\,M? (a) 3.6×10−5 M s−13.6\times10^{-5}\,\text{M\,s}^{-1} (b) 9.0×10−4 M s−19.0\times10^{-4}\,\text{M\,s}^{-1} (c) 1.2×10−4 M s−11.2\times10^{-4}\,\text{M\,s}^{-1} (d) 3.6×10−4 M s−13.6\times10^{-4}\,\text{M\,s}^{-1}

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