At 400 K the equilibrium constant for the gas-phase reaction is 4.0

CHEMISTRY · Single correct · A Level · Chemistry · Chemical equilibria (Le Chatelier’s principle and Kc) · Chemical equilibria (Le Chatelier’s principle and Kc)

Problem

At 400 K the equilibrium constant KpK_p for the gas-phase reaction 2 A(g)  ⇌  B(g)+C(g)2\,\text{A}(g) \;\rightleftharpoons\; \text{B}(g) + \text{C}(g) is 4.0. A sealed container initially contains 1.0 atm of A, 1.0 atm of B, and no C. Which of the following best describes how the partial pressures change as the system moves toward equilibrium? (a) pAp_\text{A} increases, pBp_\text{B} decreases, and pCp_\text{C} decreases (b) pAp_\text{A} decreases, pBp_\text{B} decreases, and pCp_\text{C} increases (c) pAp_\text{A} decreases, while pBp_\text{B} and pCp_\text{C} both increase (d) pAp_\text{A} decreases, pBp_\text{B} increases, and pCp_\text{C}\;\text{remains essentially unchanged}

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