At 298 K the following equilibria involve only gaseous species

CHEMISTRY · Single correct · A Level · Chemistry · Gaseous equilibria (Kp) · Gaseous equilibria (Kp)

Problem

At 298 K the following equilibria involve only gaseous species. 1. 2 NO2(g)  ⇌  N2O4(g)2\,\mathrm{NO_2}(g)\;\rightleftharpoons\;\mathrm{N_2O_4}(g) Kc1=1.5K_{c1}=1.5 2. N2O4(g)  ⇌  N2O3(g)+12 O2(g)\mathrm{N_2O_4}(g)\;\rightleftharpoons\;\mathrm{N_2O_3}(g)+\dfrac{1}{2}\,\mathrm{O_2}(g) Kp2=0.25K_{p2}=0.25 Using R=0.0821 L atm mol−1 K−1R=0.0821\,\mathrm{L\,atm\,mol^{-1}\,K^{-1}}, what is KpK_p for the overall reaction 2 NO2(g)  ⇌  N2O3(g)+12 O2(g)2\,\mathrm{NO_2}(g)\;\rightleftharpoons\;\mathrm{N_2O_3}(g)+\dfrac{1}{2}\,\mathrm{O_2}(g) at 298 K? (a) 3.8×10−33.8\times10^{-3} (b) 1.5×10−21.5\times10^{-2} (c) 3.8×10−13.8\times10^{-1} (d) 6.1×10−26.1\times10^{-2}

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