MgO melts at a temperature more than 1500 °C higher than that of NaCl

CHEMISTRY · Single correct · ISC · Chemistry · Chemical Bonding and Molecular Structure · Chemical Bonding and Molecular Structure

Problem

MgO melts at a temperature more than 1500 °C higher than that of NaCl. Which statement best accounts for this difference? (a) Because the Mg2+\mathrm{Mg^{2+}} ion is considerably smaller than Na+\mathrm{Na^{+}}, the ions in MgO are packed more closely together, giving stronger ionic attractions that require a higher melting temperature. (b) The Mg2+\mathrm{Mg^{2+}} and O2−\mathrm{O^{2-}} ions in MgO carry twice the charge of the ions in NaCl, producing much stronger Coulombic attractions that require more energy to break. (c) MgO forms a three-dimensional covalent network, whereas NaCl is held together only by ionic attractions. (d) Because MgO has a greater molar mass than NaCl, its London dispersion forces are significantly stronger.

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