The following balanced reactions occur under standard conditions (298 K, 1 atm)

CHEMISTRY · Multi-part · A Level · Chemistry · Thermodynamics · Thermodynamics

Problem

The following balanced reactions occur under standard conditions (298 K, 1 atm). Reaction I: 2 KClO₃(s) → 2 KCl(s) + 3 O₂(g) Reaction II: N₂(g) + 3 H₂(g) → 2 NH₃(g) Reaction III: C₆H₁₂O₆(s) → 2 C₂H₅OH(l) + 2 CO₂(g) (1) (a) Predict and justify the sign of ΔS° for Reaction I. (2) (a) Predict and justify the sign of ΔS° for Reaction II. (3) (a) Predict and justify the sign of ΔS° for Reaction III. (4) (b) Rank Reactions I–III from largest positive to most negative ΔS°, with justification.

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