For the reaction at a certain temperature,

CHEMISTRY · Single correct · AP · Chemistry · Equilibrium · Equilibrium

Problem

For the reaction CO(g)+Cl2(g)  ⇌  COCl2(g)\text{CO}(g)+\text{Cl}_2(g)\;\rightleftharpoons\;\text{COCl}_2(g) at a certain temperature, Kc=1.2×103K_c = 1.2\times10^{3}. A mixture is prepared with the following concentrations: [CO]=0.10 M[\text{CO}] = 0.10\,\text{M}, [Cl2]=0.050 M[\text{Cl}_2] = 0.050\,\text{M}, and [COCl2]=0.40 M[\text{COCl}_2] = 0.40\,\text{M}. Which of the following gives the value of QcQ_c for this mixture and predicts how the concentration of phosgene (COCl2\text{COCl}_2) will change as equilibrium is approached? (a) Qc=1.3×10−2;  [COCl2] will increaseQ_c = 1.3\times10^{-2};\;[\text{COCl}_2]\text{ will increase} (b) Qc=1.6×103;  [COCl2] will decreaseQ_c = 1.6\times10^{3};\;[\text{COCl}_2]\text{ will decrease} (c) Qc=8.0×101;  [COCl2] will increaseQ_c = 8.0\times10^{1};\;[\text{COCl}_2]\text{ will increase} (d) Qc=8.0×101;  [COCl2] will decreaseQ_c = 8.0\times10^{1};\;[\text{COCl}_2]\text{ will decrease}

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