The decomposition of hydrogen peroxide in aqueous solution is observed to proceed…

CHEMISTRY · Single correct · A Level · Chemistry · Introduction to organic chemistry · Introduction to organic chemistry

Problem

The decomposition of hydrogen peroxide in aqueous solution is observed to proceed rapidly in the presence of iodide ion. A suggested mechanism is shown. Step 1 (slow): H2O2(aq) + I⁻(aq) → H2O(l) + IO⁻(aq) Step 2 (fast): H2O2(aq) + IO⁻(aq) → H2O(l) + O2(g) + I⁻(aq) Which of the following species acts as a catalyst for the overall reaction? (a) IO− (aq)\mathrm{IO^-\,(aq)} (b) I− (aq)\mathrm{I^-\,(aq)} (c) H2O2 (aq)\mathrm{H_2O_2\,(aq)} (d) O2 (g)\mathrm{O_2\,(g)}

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