For the reaction 2NO (g) ⇌ N O (g)

CHEMISTRY · Single correct · A Level · Chemistry · Chemical equilibria (Le Chatelier’s principle and Kc) · Chemical equilibria (Le Chatelier’s principle and Kc)

Problem

For the reaction 2NO2_2 (g) ⇌ N2_2O4_4 (g), a student’s particulate diagram shows only N2O4\text{N}_2\text{O}_4 molecules in the container. Which of the following best explains why this diagram does NOT depict a system at equilibrium? (a) Because the balanced equation contains a 2 : 1 coefficient ratio, the container should display twice as many NO2\text{NO}_2 molecules as N2O4\text{N}_2\text{O}_4 at equilibrium. (b) A correct equilibrium diagram must show equal numbers of NO2\text{NO}_2 and N2O4\text{N}_2\text{O}_4 particles. (c) Both NO2\text{NO}_2 and N2O4\text{N}_2\text{O}_4 must be present because the forward and reverse reactions occur simultaneously at equilibrium. (d) At equilibrium the reaction stops, so a correct diagram would show no further collisions or molecular changes.

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