During the freezing of a solution at its f.pt.

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Problem

During the freezing of a solution at its f.pt., which of the equilibrium exists? (1) Solution(l)⇌Solid solution(s)\text{Solution}_{(l)} \rightleftharpoons \text{Solid solution}_{(s)} (2) Solvent(l)⇌Solvent(s)\text{Solvent}_{(l)} \rightleftharpoons \text{Solvent}_{(s)} (3) Solution(l)⇌Solute(s)+Solvent(s)\text{Solution}_{(l)} \rightleftharpoons \text{Solute}_{(s)} + \text{Solvent}_{(s)} (4) Solution(l)⇌Solute(s)+Solvent(l)\text{Solution}_{(l)} \rightleftharpoons \text{Solute}_{(s)} + \text{Solvent}_{(l)}

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