Consider a galvanic cell constructed at 298 K from the half-reactions below

CHEMISTRY · Single correct · AP · Chemistry · Thermodynamics and Electrochemistry · Thermodynamics and Electrochemistry

Problem

Consider a galvanic cell constructed at 298 K from the half-reactions below. Cl₂(g) + 2 e⁻ → 2 Cl⁻  E° = +1.36 V Zn²⁺ + 2 e⁻ → Zn(s)  E° = –0.76 V Solutions in both compartments are 1.0 M in their respective ions. If the observed cell potential is 2.05 V, which of the following is the partial pressure of Cl₂(g) in the chlorine compartment? (a) 9.4×10−2 atm9.4 \times 10^{-2}\ \text{atm} (b) 2.6×10−1 atm2.6 \times 10^{-1}\ \text{atm} (c) 4.3×10−3 atm4.3 \times 10^{-3}\ \text{atm} (d) 6.6×10−2 atm6.6 \times 10^{-2}\ \text{atm}

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