For the gas-phase reaction NO₂(g) + CO(g) → NO(g) + CO₂(g)

CHEMISTRY · Subjective · AP · Chemistry · Kinetics · Kinetics

Problem

For the gas-phase reaction NO₂(g) + CO(g) → NO(g) + CO₂(g), two mechanisms are proposed. Mechanism A: Step 1 NO₂ + NO₂ → NO₃ + NO Step 2 NO₃ + CO → NO₂ + CO₂ Mechanism B: Single step NO₂ + CO → NO + CO₂ During the reaction, NO₃(g) is detected only while the reactants are being consumed and is absent from the final mixture. Explain why this observation supports Mechanism A rather than Mechanism B.

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