At 25 °C, Indicator X has and Indicator Y has

CHEMISTRY · Subjective · CBSE · Chemistry · Acids, Bases and Salts · Acids, Bases and Salts

Problem

At 25 °C, Indicator X has pKa=6.3pK_a = 6.3 and Indicator Y has pKa=8.1pK_a = 8.1. The pKapK_a of each indicator decreases by 0.015 pH units per °C rise in temperature. A titration that has an equivalence-point pH of 7.8 is to be performed at 40 °C. Which indicator will provide the more accurate endpoint? (Show the adjusted pKapK_a values in your reasoning.)

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