The molar volume of liquid benzene (density = ) increases by a factor of 2750 as it…

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Problem

The molar volume of liquid benzene (density = 0.877 g mL−10.877 \text{ g mL}^{-1} ) increases by a factor of 2750 as it vaporises at 20∘C20^\circ\text{C} and that of liquid toluene (density 0.867 g mL−10.867 \text{ g mL}^{-1} ) increases by a factor of 7720 at 20∘C20^\circ\text{C} . A solution of benzene and toluene at 20∘C20^\circ\text{C} has a vapour pressure of 46.0 torr. Find the mole fraction of benzene in the vapour above the solution.

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