A sample of water at is contained in an insulated calorimeter of negligible heat capacity

PHYSICS · Single correct · AP · Physics 2: Algebra-based · Thermodynamics · Thermodynamics

Problem

A 100 g100\,\text{g} sample of water at 25.0 ∘C25.0\,^{\circ}\text{C} is contained in an insulated calorimeter of negligible heat capacity. A 10.0 g10.0\,\text{g} piece of metal at 95.0 ∘C95.0\,^{\circ}\text{C} is added. After thermal equilibrium is reached, the final temperature of the water–metal system is 27.0 ∘C27.0\,^{\circ}\text{C}. Which statement best accounts for the energy changes in this experiment? (a) qmetalq_{\text{metal}} is negative, qwaterq_{\text{water}} is positive, but ∣qmetal∣<∣qwater∣|q_{\text{metal}}| < |q_{\text{water}}| because the water sample has the larger mass. (b) qmetalq_{\text{metal}} is positive, qwaterq_{\text{water}} is negative, and ∣qmetal∣>∣qwater∣|q_{\text{metal}}| > |q_{\text{water}}| because the metal undergoes the larger temperature change. (c) qmetalq_{\text{metal}} is negative, qwaterq_{\text{water}} is positive, and ∣qmetal∣=∣qwater∣|q_{\text{metal}}| = |q_{\text{water}}| because energy lost by the metal equals the energy gained by the water. (d) qmetalq_{\text{metal}} is negative, qwaterq_{\text{water}} is positive, and ∣qmetal∣>∣qwater∣|q_{\text{metal}}| > |q_{\text{water}}| because metals generally have larger specific heats.

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