A 25.0 mL sample of 0.120 M monoprotic acid HX ( ) is titrated with 0.180 M Ba(OH)

CHEMISTRY · Multi-part · A Level · Chemistry · Acids and bases · Acids and bases

Problem

A 25.0 mL sample of 0.120 M monoprotic acid HX (Ka=3.5×10−6K_a=3.5\times10^{-6}) is titrated with 0.180 M Ba(OH)2_2. Respond thoroughly to each part. (a) Write the balanced molecular equation for the reaction between HX and Ba(OH)2_2. (b) Calculate the exact volume of 0.180 M Ba(OH)2_2 required to reach the equivalence point. (c) Suppose that an additional 20.0 mL of the 0.180 M Ba(OH)2_2 is delivered beyond the equivalence point. Calculate the pH of the final solution. (d) Provide a quantitative argument to justify neglecting any contribution of the conjugate base X−^- when you calculated the pH in part (c).

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