An analyst prepared an aqueous nitrite standard with an actual concentration of

CHEMISTRY · Subjective · AP · Chemistry · Properties of Substances and Mixtures · Properties of Substances and Mixtures

Problem

An analyst prepared an aqueous nitrite standard with an actual concentration of 1.00×10−4 M1.00\times10^{-4}\,\text{M}. Using a 1.00 cm1.00\,\text{cm} cuvette at 540 nm540\,\text{nm} (ε=4.20×103 L mol−1 cm−1\varepsilon = 4.20\times10^{3}\,\text{L}\,\text{mol}^{-1}\,\text{cm}^{-1}), the absorbance recorded was 0.4300.430. Calculate the percent error in the analyst’s concentration determination based on this measurement, relative to the true concentration.

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