For the reaction

CHEMISTRY · Subjective · A Level · Chemistry · Chemical equilibria (Le Chatelier’s principle and Kc) · Chemical equilibria (Le Chatelier’s principle and Kc)

Problem

For the reaction H2(g)+I2(g)  ⇌  2 HI(g) \text{H}_2(g)+\text{I}_2(g)\;\rightleftharpoons\;2\text{ HI}(g), the equilibrium constant at 450 ∘C450\,^{\circ}\text{C} is Kc=64K_c = 64. Particle counts were recorded at two times in the same 2.0 L2.0\,\text{L} container: • t1t_1: 5 H2_2, 5 I2_2, 40 HI • t2t_2: 3 H2_2, 3 I2_2, 30 HI At which time is the system at equilibrium? Justify your answer by comparing QcQ_c to KcK_c for each time.

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