The hypochlorite ion reacts with iodide ion in aqueous solution according to the…

CHEMISTRY · Multi-part · A Level · Chemistry · Rate equations · Rate equations

Problem

The hypochlorite ion reacts with iodide ion in aqueous solution according to the stoichiometry ClO⁻(aq) + 2 I⁻(aq) → I₂(aq) + Cl⁻(aq). Initial-rate data at 298 K are listed.
Trial[ClO⁻]₀ (M)[I⁻]₀ (M)Initial rate (mol·L⁻¹·s⁻¹)
10.0100.0204.8 × 10⁻⁴
20.0200.0209.6 × 10⁻⁴
30.0200.0403.84 × 10⁻³
(a) Determine the reaction order with respect to ClO⁻ and to I⁻. Support each order with a quantitative comparison of trials. (b) Write the complete rate law, including the rate constant. (c) Using each trial, calculate an individual value of k. Show numerical work and units. (d) Compute the mean k and comment on the consistency of the experimental values. Identify one possible experimental source of the small variation you observe.

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