1.6 g pyrolusite ore was titrated with 50 cm3 of 1.0 N oxalic acid and some sulphuric acid. The oxalic acid left was raised to 250 mL in a flask. 25 mL of this solution when treated with 0.1 N KMnO4 required 32 mL of the solution. The percentage of available oxygen in pyrolusite is :