At 298 K the equilibrium constant for is

CHEMISTRY · Single correct · AP · Chemistry · Equilibrium · Equilibrium

Problem

At 298 K the equilibrium constant for N2O4(g)⇌2 NO2(g)\mathrm{N_2O_4}(g) \rightleftharpoons 2\,\mathrm{NO_2}(g) is Kc=0.36K_c = 0.36. A reaction mixture is prepared with [N2O4]=0.15 M[\mathrm{N_2O_4}] = 0.15\,\text{M} and [NO2]=0.60 M[\mathrm{NO_2}] = 0.60\,\text{M}. Which statement correctly compares QcQ_c with KcK_c and predicts the spontaneous direction of shift? (a) Qc<KcQ_c < K_c; the mixture will shift toward NO2\mathrm{NO_2}. (b) Qc>KcQ_c > K_c; the mixture will shift toward N2O4\mathrm{N_2O_4}. (c) Qc=KcQ_c = K_c; the mixture is already at equilibrium. (d) Qc>KcQ_c > K_c; the mixture will shift toward NO2\mathrm{NO_2}.

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