The rate of formation of the complex at 25°C following the reaction: is given as :…

CHEMISTRY · Subjective · ISC · Chemistry · Coordination Compounds · Coordination Compounds

Problem

The rate of formation of the complex [Fe(dipy)3]2+[Fe(dipy)_3]^{2+} at 25°C following the reaction: Fe2++3dipy⇌[Fe(dipy)3]2+Fe^{2+} + 3 dipy \rightleftharpoons [Fe(dipy)_3]^{2+} is given as : rate=1.45×1013[Fe2+][dipy]3rate = 1.45 \times 10^{13} [Fe^{2+}] [dipy]^3 The rate of disappearance of complex is given as : rate=1.22×10−4[Fe(dipy)3]2+rate = 1.22 \times 10^{-4} [Fe(dipy)_3]^{2+} Calculate the stability constant of complex. *dipy* is abbreviated for dipyridyl a chelating agent.

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