Which of the following changes would MOST increase the likelihood that a termolecular…

CHEMISTRY · Single correct · A Level · Chemistry · Kinetics · Kinetics

Problem

Which of the following changes would MOST increase the likelihood that a termolecular elementary step could become the rate-determining step of a gas-phase reaction? (a) Adding an inert gas at constant pressure to increase the total volume of the reaction vessel (b) Raising the temperature from 298 K298\,\text{K} to 600 K600\,\text{K} while keeping the pressure constant (c) Raising the total pressure of the reaction mixture by a factor of 1000 while keeping the temperature constant (d) Lowering the temperature from 298 K298\,\text{K} to 200 K200\,\text{K} to reduce molecular speeds

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