At 298 K the equilibrium (g) ⇌ 2 (g) exists in a closed container

CHEMISTRY · Single correct · A Level · Chemistry · Chemical equilibria (Le Chatelier’s principle and Kc) · Chemical equilibria (Le Chatelier’s principle and Kc)

Problem

At 298 K the equilibrium N2O4N_{2}O_{4}(g) ⇌ 2 NO2NO_{2}(g) exists in a closed container. A sudden injection of NO2NO_{2} gas instantly doubles its concentration, leaving temperature unchanged. Which statement best predicts the system’s response as it re-establishes equilibrium? (a) [N2O4N_{2}O_{4}] will increase and the final KK value will be larger. (b) [N2O4N_{2}O_{4}] will decrease and KK remains unchanged. (c) [N2O4N_{2}O_{4}] will increase while KK remains unchanged. (d) [N2O4N_{2}O_{4}] will remain constant because only NO2NO_{2} was added.

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