Two independent quantities for copper at its melting point,

PHYSICS · Multi-part · Fermi University Physics · Thermal, Statistical & Complex Systems · Condensed Matter, Materials & Soft Matter · Crystal structure, bonding and diffraction

Condensed Matter Physics, Ch Real crystals: vacancies, dislocations and the strength of metals

Problem

Two independent quantities for copper at its melting point, 1358 K1358\ \mathrm{K}, are both set by a Boltzmann factor e−E/kBTe^{-E/k_BT}: the equilibrium vacancy fraction (Section 13.2, εv=1.28 eV\varepsilon_v = 1.28\ \mathrm{eV}), and, for a vibrational mode of energy quantum ℏω=25 meV\hbar\omega = 25\ \mathrm{meV}, the ratio of the population of its first excited level to its ground level, e−ℏω/kBTe^{-\hbar\omega/k_BT} (Chapter 6). ((a)) Compute the vacancy fraction nvn_v at 1358 K1358\ \mathrm{K}. ((b)) Compute the oscillator's population ratio at the same temperature. ((c)) Which is larger, and by roughly what factor? Explain in one sentence, in terms of the two energies compared with kBTk_BT, why the same mathematical form gives such different-sized answers.

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