A strand between two cross-links has links of length .

PHYSICS · Multi-part · Fermi University Physics · Condensed Matter, Materials & Soft Matter · Soft condensed matter · Soft condensed matter

Condensed Matter Physics, Ch Soft matter: when entropy, not bonding, sets the structure

Problem

A strand between two cross-links has Nmon=800N_{\rm mon}=800 links of length bmon=0.50 nmb_{\rm mon}=0.50\,\mathrm{nm}. ((a)) Starting from F(ree)=32kBTNmonbmon2ree2F(r_{\rm ee})=\tfrac32\dfrac{k_BT}{N_{\rm mon}b_{\rm mon}^2}r_{\rm ee}^2, derive the stiffness KchK_{\rm ch} of this strand at 300 K300\,\mathrm{K}. ((b)) Find the force needed to hold its ends at three times its natural size Ree=bmonNmonR_{\rm ee}=b_{\rm mon}\sqrt{N_{\rm mon}}.

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