PHYSICS · Multi-part · Fermi University Physics · Quantum Mechanics · Atomic, Molecular & Optical Physics · One-electron atoms and the origins of atomic structure
Deriving the Spectrum, Ch Fine structure and the Lamb shift
Problem
He+ (Z=2) has one electron, so its 1S and 2S levels follow the same fine-structure formula as hydrogen's. Ignore the difference between its reduced mass and hydrogen's, take En=−Z2hcRH/n2 with cRH=3.28805×106GHz, and take α=1/137.036.
((a)) Using the shift of an s level, 2mc2En2(3−4n), and En/mc2=−(Zα)2/2n2, find how far fine structure moves the 1S and 2S levels of He+, in GHz.
((b)) Hence find how much fine structure widens the 1S-2S interval, and compare with the 30.1GHz by which it widens hydrogen's.
((c)) A non-relativistic treatment was expected to miss a fraction of order (Zα)2 of this interval, 43Z2cRH. What fraction of that scale does the fine-structure widening actually reach?