Deriving the Spectrum, Ch Atoms in magnetic fields
Problem
(a) A hydrogen 1s atom sits in a uniform field B=4T. Using the fact that at 1T the paramagnetic shift of hydrogen 1s is μBB=58μeV and the diamagnetic shift is 0.12neV, estimate both shifts at 4T. (b) The ground state of 87Rb (I=3/2) has J=1/2 with gJ=2. Neglecting the nuclear term, find gF for the hyperfine level F=2 using the projection theorem result gF≈gJ2F(F+1)F(F+1)+J(J+1)−I(I+1).