The thick-base estimate fails in a wafer that is not thick compared with
PHYSICS · Multi-part · Fermi University Physics · Condensed Matter, Materials & Soft Matter · Earth, Climate & Energy Physics · Semiconductor physics and devices
Energy from Physics, Ch The illuminated junction: generation, collection and the cell's characteristic
Problem
The thick-base estimate fc(x)≈e−x/L fails in a wafer that is not thick compared with L, where the rear surface decides. In a base of thickness W with the junction at x=0, the collection probability of a pair born at depth x obeys the same equation as an excess of minority carriers in the dark, Dd2fc/dx2−fc/τ=0, with fc(0)=1 at the junction. A perfectly passivated rear loses no carriers, so dfc/dx=0 at x=W; an ohmic rear contact recombines every carrier that reaches it, so fc(W)=0. Take W=180μm, L=187μm and 1000nm light with absorption length 1/α=156μm, entering at the front (reflection already excluded) and making a single pass through the wafer.
((a)) Solve for fc(x) with each rear, and check both against the far-side values 0 and 0.67 quoted for this wafer in the text.
((b)) Find the fraction of entering photons whose pairs are collected, ∫0Wαe−αxfc(x)dx, with each rear and with the thick-base estimate cut off at x=W.
((c)) Find the fraction of entering photons absorbed at all, and hence the share of absorbed photons collected with each rear. Once the rear is passivated, which is the larger loss: light passing straight through, or pairs lost to recombination?