Potassium vapour in a discharge lamp has a total atom density (neutrals plus ions) of…

PHYSICS · Multi-part · Fermi University Physics · Plasma Physics · The plasma state and single-particle motion · The plasma state and single-particle motion

Plasma Physics, Ch What makes an ionised gas a plasma: shielding, the plasma parameter and the natural frequencies

Problem

Potassium vapour in a discharge lamp has a total atom density (neutrals plus ions) of n=1.0×1022 m−3n = 1.0\times10^{22}\,\mathrm{m^{-3}} and a temperature of T=2500 KT = 2500\,\mathrm{K}. The first ionisation energy of potassium is U=4.34 eVU = 4.34\,\mathrm{eV}. The neutral atom's ground state has degeneracy gn=2g_n = 2 and the ion's ground state has degeneracy gi=1g_i = 1, the same ratio as for hydrogen, so the Saha equation may be evaluated with the same constant, 2gi/gn×(2πmekBT/h2)3/2=2.41×1021 T[K]3/2 m−32g_i/g_n \times (2\pi m_ek_BT/h^2)^{3/2} = 2.41\times10^{21}\,T[\mathrm{K}]^{3/2}\,\mathrm{m^{-3}}. Assume the potassium is the only appreciable source of free electrons, so that ne=nin_e = n_i. ((a)) Assuming the vapour is in Saha equilibrium, find the fractional ionisation x=ni/nx = n_i/n. ((b)) State, in one sentence, why this fraction is not negligible even though kBTk_BT is only about one twentieth of UU.

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