A closed metal box whose walls are at room temperature, K

PHYSICS · Multi-part · Fermi University Physics · Quantum Mechanics · Origins of quantum theory · Origins of quantum theory

Quantum Mechanics: From the Photon to the Hydrogen Atom, Ch Light in lumps: blackbody radiation, the photoelectric effect and Compton scattering

Problem

A closed metal box whose walls are at room temperature, T=300T=300 K, is filled with thermal radiation. The energy density per unit frequency interval is, according to Planck,u(ν)=8πhν3c3 1ehν/kBT−1,u(\nu)=\frac{8\pi h\nu^{3}}{c^{3}}\,\frac{1}{e^{h\nu/k_BT}-1},while the classical law, giving each standing-wave pattern the average energy kBTk_BT, isucl(ν)=8πν2kBTc3.u_{\rm cl}(\nu)=\frac{8\pi\nu^{2}k_BT}{c^{3}} .Let x=hν/kBTx=h\nu/k_BT. Use h=6.626×10−34h=6.626\times10^{-34} J s and kB=1.381×10−23k_B=1.381\times10^{-23} J K−1^{-1}. ((a)) Show that u(ν)/ucl(ν)=x/(ex−1)u(\nu)/u_{\rm cl}(\nu)=x/(e^{x}-1), and use ex≈1+xe^{x}\approx1+x for small xx to show that the ratio tends to 11 when hν≪kBTh\nu\ll k_BT. ((b)) Evaluate the ratio at x=1x=1 and at x=5x=5, and say what each value means for the classical prediction. ((c)) Find xx and the ratio for the microwave frequency ν=30\nu=30 GHz. ((d)) Find xx and the ratio for the infrared frequency ν=30\nu=30 THz, and state which of the two frequencies a classical calculation would handle acceptably.

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